The soft colorless solid with a pungent odor was known to the alchemists as butter of antimony.Antimony trichloride is prepared by reaction of antimony trioxide acrylonitrile Prior art date 1973-08-24 Legal status (The legal status is an assumption and is not a legal conclusion. Hazard classification & labelling Hazard classification and labelling. [9], SbCl3 is only a weak Lewis base,[7] however some complexes are known for example the carbonyl complexes, Fe(CO)3(SbCl3)2 and Ni(CO)3SbCl3. ANTIMONY . ... A colorless, solid compound, toxic and corrosive. SbCl3 is readily hydrolysed and samples of SbCl3 must be protected from moisture. It is decomposed slowly by water to hydrochloric acid and antimony oxychloride. [10] In SbCl3 each Sb has three Cl atoms at 234 pm showing the persistence of the molecular SbCl3 unit, however there are a further five neighboring Cl atoms, two at 346 pm, one at 361 pm, and two at 374 pm. DATE OF LAST REVISION: 0 6/12/15. Sb3+ is bonded in a distorted T-shaped geometry to three Cl1- atoms. Antimony(III) chloride ReagentPlus ®, 99% Synonym: Antimony trichloride CAS Number 10025-91-9. to 100 cc. Molecular Weight 228.12 . The number of electrons in each of antimony's shells is 2, 8, 18, 18, 5 and its electron configuration is [Kr] … Antimony trichloride is the chemical compound with the formula SbCl3. Belongs to the Following … OSHA SDS #: 25170 rev 101 3/27/2015 ANTIMONY TRICHLORIDE TS Page 4. a: the trichloride SbCl 3 obtained as a colorless hygroscopic caustic crystalline solid from antimony and chlorine and used chiefly in coloring metals (such as iron, zinc), as a catalyst, and as a mordant — called also butter of antimony The structure is zero-dimensional and consists of four antimony trichloride molecules. Company: Angstrom Sciences, Inc. 40 South Linden Street . sodium antimonate, potassium antimonate, antimony pentoxide, antimony trichloride, tartar emetic, antimony sulfide. It is corrosive to tissue. EC Number 233-047-2. Prepared in this way it contains a small quantity of the unaltered chloride, which can be removed by ether or carbon bisulphide. During combustion at a temperature higher than 6000°F, the halogen produces hydrochloric or hydrobromic acid that reacts with the BrightSun antimony oxide. 10025-91-9: Density: 3,14 g/cm3 Solubility: H2O: soluble in water There … (HSDB, 1997) Major products of combustion When heated to decomposition antimony trichloride emits fumes of chloride and antimony. Provided is a method for producing a crystalline antimony pentoxide hydrate which can be produced and … Antimony trichloride is the chemical compound with the formula SbCl3. Antimony trichloride Revision Date 23-January-2018 Email: EMSDS.RA@thermofisher.com Creation Date 09-April-2010 Revision Date 23-January-2018 Print Date 23-January-2018 Revision Summary This document has been updated to comply with the requirements of WHMIS 2015 to align This … The antimony trichloride reacts with the carotenoid to form a blue complex that can be measured by colorimetry. The CLP Regulation makes … Its solution is used as an analytical reagent for chloral, aromatics, and vitamin A. This results in the formation of one of these compounds: antimony trichloride, antimony oxychloride, antimony tribromide or antimony oxybromide. Investigations on the mechanism of the genotoxicity of antimony trichloride in cultured human … Thermal decomposition study of antimony (III) tribromide and aromatic amine adducts. Product Name: Antimony . PubChem Substance ID … C, preferably 80.degree. SAFETY DATA SHEET . Phosphorus trioxide is the chemical compound with the molecular formula P 4 O 6.Although the molecular formula suggests the name tetraphosphorus hexoxide, the name phosphorus trioxide preceded the knowledge of the compound's molecular structure, and its usage continues today. The soft colorless solid with a pungent odor was known to the alchemists as butter of antimony. Pure SbF3 is then obtained by carefully evaporating all of the water from the crude product, which is … Mutation data reported. CAS Number: 7440-36-0 / EC Number: 231-146-5 . It also may be made by treating antimony trioxide with concentrated hydrochloric acid. SbCl3 is Cementite structured and crystallizes in the orthorhombic Pnma space group. See ANTIMONY COMPOUNDS and ANTIMONY(III) CHLORIDE.When heated to decomposition it emits very toxic fumes of Cl − and Sb. It is also used as a catalyst for polymerization, hydrocracking, and chlorination reactions; as a mordant; and in the production of other antimony salts. For more information call: 412-469-8466 (Monday - Friday 9:00 - 5:00 … 1988). In order to prevent the decomposition of antimony pentachloride into antimony trichloride and chlorine, it is advantageous to conduct the distillation of antimony pentachloride in a chlorine … Oxides of antimony. It is a white powder insoluble in water, alcohol and … Sigma-Aldrich offers a number of Antimony(III) chloride products. It is shipped as a solid or liquid solution. Decomposition Products: Thermal decomposition produces toxic vapors of hydrogen chloride, chlorine, phosgene. ANTIMONY TRICHLORIDE 99% AR/ACS Safety Data Sheet www.lobachemie.com 22/03/2019 7/10 Transport document description (IMDG) : UN 1733 ANTIMONY TRICHLORIDE, 8, II, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS Transport document description (IATA) : UN 1733 Antimony trichloride, 8, II, … C. The distillation is preferably conducted under a pressure of between 20 and 130 mmHg. to 130.degree. In episode 12 of the third season of the popular British program All Creatures Great and Small (adapted from chapter six of the book All Things Wise and Wonderful), several calves died following an episode of nonspecific gastroenteritis, the cause of which was later determined to be ingestion of antimony trichloride present in a solution used to dissolve their horn stubs. Antimony trifluoride is a white to gray crystalline solid, which is sometimes shipped as an aqueous solution. It is suggested in that SbCIa is formed due to a three stage endothermic decomposition of antimony oxychloride, formed during the reaction of antimony oxide with hydrogen chloride evolved during the decomposition of the organic chloro-compound. Made by adding 30 gm having to cut them off these eight atoms be... A polymeric anion of composition [ SbCl52− ] n with distorted octahedral SbIII, phosgene CAS, MSDS more. Ts Page 4 in a distorted T-shaped geometry to three Cl1- atoms see antimony compounds and.! 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