Warning; Hazard Category. [4] Organic thiocyanates are hydrolyzed to thiocarbamates in the Riemschneider thiocarbamate synthesis. The determination of Co(II) in the presence of Fe(III) is possible by adding KF to the solution, which forms uncoloured, very stable complexes with Fe(III), which no longer react with SCN−. 592-88-1. [citation needed]. Precautionary Statement. SECTION 2 — HAZARDS IDENTIFICATION. Similarly, this reaction is used as a test for Fe3+ in the laboratory. Potassium thiocyanate MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. 105125 View Pricing & Availability. [16], If [SCN]− is added to a solution with iron(III) ions, a blood-red solution forms mainly due to the formation of [Fe(SCN)(H2O)5]2+, i.e. 2. It facilitates the ring opening of aziridines with high regioselectivity. Mercury(II) thiocyanate was formerly used in pyrotechnics. … Causes eye irritation … Wear protective gloves/ protective clothing. Potassium thiocyanate CAS Number: 333-20-0: Molecular Weight: 97.181: Density: 1.886: Boiling Point: 500°C: Molecular Formula: CKNS: Melting Point: 173 °C(lit.) Download Product Safety Card; … When the hands are brought into contact, the solutions react and the effect looks remarkably like stigmata. Response: Not applicable. The compound has a low melting point relative to most other inorganic salts. EC Number 206-370-1. Storage: Not applicable. Its crystalline structure has been analyzed based on polarized infrared spectral data. EUH032-Contact with acids liberates very toxic gas. Precautionary Statement Ph Eur CAS #: 333-20-0 Molar Mass: 97.18 g/mol Chemical Formula: KSCN Hill Formula: CKNS. Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. When in contact with ferric chloride solution (or other solutions containing Fe3+), the product of the reaction is a solution with a blood red colour, due to the formation of the thiocyanatoiron complex ion. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10190 Signal Word WARNING. [6][7][8] Thus the complete absence of thiocyanate or reduced thiocyanate[9] in the human body, (e.g., cystic fibrosis) is damaging to the human host defense system. 4 (H332) Aquatic Chronic 3 (H412) (EUH032) Xn; R20/21/22 R32 R52-53 For the full text of the R-phrases and H-Statements mentioned in this Section, … Molecular Weight 97.18 . Hazard Statements: Not applicable. Molecular Weight 97.18 . It is an important salt of the thiocyanate anion, one of the pseudohalides. 490563 Sigma-Aldrich. It is a green-brown solid and its crystal structure was determined first in 1982. EC Number 206-370-1. [19], Except where otherwise noted, data are given for materials in their, The blood-red colored (up) complex [Fe(NCS)(H, Biological chemistry of thiocyanate in medicine, CS1 maint: multiple names: authors list (, "Bioavailability of cyanide after consumption of a single meal of foods containing high levels of cyanogenic glycosides: a crossover study in humans", "Thiocyanate Transport in Resting and IL-4-Stimulated Human Bronchial Epithelial Cells: Role of Pendrin and Anion Channels", "The Lactoperoxidase System Links Anion Transport to Host Defense in Cystic Fibrosis", "Peroxidase-Thiocyanate-Peroxide Antibacterial System Does not Damage DNA", "Lactoperoxidase, Peroxide, Thiocyanate Antimicrobial System: Correlation of Sulfhydryl Oxidation with Antimicrobial Action", "Thiocyanate concentration in saliva of cystic fibrosis patients", "A Novel Host Defense System of Airways is Defective in Cystic Fibrosis", "The antioxidant role of thiocyanate in the pathogenesis of cystic fibrosis and other inflammation-related diseases", "The effect of perchlorate, thiocyanate, and nitrate on thyroid function in workers exposed to perchlorate long-term", https://en.wikipedia.org/w/index.php?title=Thiocyanate&oldid=991810105, Articles with dead external links from June 2018, Articles with permanently dead external links, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Articles with unsourced statements from February 2019, Creative Commons Attribution-ShareAlike License, This page was last edited on 1 December 2020, at 22:58. Organic and transition metal derivatives of the thiocyanate ion can exist as "linkage isomers". KSCN is also the starting product for the synthesis of carbonyl sulfide. Potassium thiocyanate is the chemical compound with the molecular formula KSCN. Organic compounds containing the functional group SCN are also called thiocyanates. Signal Word. From Wikipedia, the free encyclopedia Nickel (II) thiocyanate is a coordination polymer with formula Ni (SCN) 2. The inhibition efficiency of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been evaluated. Supplemental … Other factors, e.g. It is the conjugate base of thiocyanic acid. H412-Harmful to aquatic life with long lasting effects. Experimental evidence leads to the general conclusion that class A metals (hard acids) tend to form N-bonded thiocyanate complexes, whereas class B metals (soft acids) tend to form S-bonded thiocyanate complexes. Detail>> 420-04-2. cyanamide. Toxicity Statement: Not … Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Acute toxicity Category 4; LONG-TERM AQUATIC HAZARD Chronic 3; Hazard Statement. pentaaqua(thiocyanato-N)iron(III). Beilstein/REAXYS Number 3594799 . H302-Harmful if swallowed. P270 - Do not eat, drink or smoke when using this product. Thiocyanate shares its negative charge approximately equally between sulfur and nitrogen. Since thiocyanates will decrease iodide transport into the thyroid follicular cell, they will decrease the amount of thyroxine produced by the thyroid gland. EUH032-Contact with acids liberates very toxic gas. SECTION 2 — HAZARDS IDENTIFICATION. Fe(SCN)3 and [Fe(SCN)4]−. Download Product Safety Card; Recommended … 105124 View Pricing & Availability. Substance identity Substance identity. Potassium Thiocyanate Flinn Scientific, Inc. P.O. [3] For this purpose, the KSCN is first melted under vacuum to remove water. [14] Sodium nitroprusside, a metabolite of which is thiocyanate, is however still used for the treatment of a hypertensive emergency. Sodium thiocyanate may be used as a reducing agent in the preparation of monodisperse gold oligoclusters. Signal word (GHS US) : Warning Hazard statements (GHS US) : H272 - May intensify fire; oxidizer H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation Precautionary statements (GHS US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. Safety Information. Packaging 50, 250 g in poly bottle Safety & Documentation. Diallyl sulfide. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10191 Signal Word WARNING SECTION 2 — HAZARDS IDENTIFICATION Hazard class: Skin corrosion or irritation (Category 3). MSDS: Chinese USA: Flash Point: 500°C: Symbol: GHS07: Signal Word: Warning × In a related reaction, KSCN converts cyclohexene oxide to the corresponding episulfide.[4]. Hazard class: Serious eye damage or irritation (Category 2B). Potassium thiocyanate, "ATP1 to CLP" Implementation: EU Remarks: CLP Annex VI table 3.1 (ATP to CLP 790/2009 of 10 August 2009): 615-004-00-3 "salts of thiocyanic acid, with the exception of those specified elsewhere in this Annex". Aqueous KSCN reacts almost quantitatively with Pb(NO3)2 to give Pb(SCN)2, which has been used to convert acyl chlorides to isothiocyanates. Infobox references: Cobalt(II) thiocyanate … Potassium thiocyanate is the chemical compound with the molecular formula KSCN. H332-Harmful if inhaled. [citation needed], Phospholipids or some detergents aid the transfer of thiocyanatoiron into chlorinated solvents like chloroform and can be determined in this fashion. It is the conjugate base of thiocyanic acid. H302, H312, H332, H410: GHS precautionary statements . Potassium thiocyanate. Rhodanese catalyzes the reaction of sodium nitroprusside with thiosulfate to form the metabolite thiocyanate. Thiocyanate (also known as rhodanide) is the anion [SCN]−. Pictograms: Not applicable. 333-20-0. potassium thiocyanate. Recent experimental and theoretical results have firmly established the existence of enhanced concentrations of selected ions at the air/water interface. It can be painted onto a surface or kept as a colorless solution. what is ?) The Brief Profile summarizes the non-confidential data on substances as it is held in the databases of the European Chemicals Agency (ECHA), including data provided by third parti P280 Wear protective gloves/protective clothing/ eye protection/face protection. H332-Harmful if inhaled. 77, No. AgSCN is monoclinic with 8 molecules per unit cell. Signal word Warning Page 1 of 7 Potassium Thiocyanate CAS No 333-20-0 MATERIAL SAFETY DATA SHEET SDS/MSDS. Label elements Signal Word Warning Hazard Statements H412 - Harmful to aquatic life with long lasting effects H302 - Harmful if swallowed H332 - Harmful if inhaled H312 - Harmful in contact with skin EUH032 - Contact with acids liberates very toxic gas Precautionary Statements Avoid release to the environment. Signal Word Warning Hazard Statement H332 Harmful if inhaled H312 Harmful in contact with skin H302 Harmful if swallowed H412 Harmful to aquatic life with long-lasting effects Precautionary Statement P273 Avoid release to the environment. Potassium thiocyanate-13C 99 atom % 13C | Sigma-Aldrich. … [17], Similarly, Co2+ gives a blue complex with thiocyanate. Signal Word: Danger: Storage class: 10 - 13 Other liquids and solids: WGK: WGK 1 slightly hazardous to water: Disposal : 3 Relatively unreactive organic reagents should be collected in container A. As a consequence, thiocyanate can act as a nucleophile at either sulfur or nitrogen — it is an ambidentate ligand. Hazard class: Acute toxicity, oral, dermal, and inhalation (Category 4). It is an important salt of the thiocyanate anion, one of the pseudohalides. If halogenated, they should be collected in container B. Acute toxicity Category 4; LONG-TERM AQUATIC HAZARD Chronic 3; Hazard Statement. Organic compounds containing the functional group SCN are also called thiocyanates. Symbol GHS05,GHS07. SDS; CoA; Synonyms: Potassium sulfocyanide EC Number: 206-370-1 Grade: ACS,ISO,Reag. 0. Hazard statement(s ) H302 + H312 + H332 H412 Precautionary statement(s ) P273 P280 Harmful if swallowed, in contact with skin or if inhaled Harmful to aquatic life with long lasting effects. Use in chemical synthesis Signal Word Warning Hazard Statements H272 - May intensify fire; oxidizer Precautionary Statements P280 - Wear protective gloves/protective clothing/eye protection/face protection P221 - Take any precaution to avoid mixing with combustibles P371 + P380 + P375 - In case of major fire and large quantities: Evacuate area. [10][11], Thiocyanate is a potent competitive inhibitor of the thyroid sodium-iodide symporter. In thiocyanates, the organic group (or metal ion) is attached to sulfur: R−S−C≡N has a S–C single bond and a C≡N triple bond. [12] Iodine is an essential component of thyroxine. 333-20-0. potassium thiocyanate. Potassium thiocyanate ( kalium tiosianat ) MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Infobox references: Structure. Thiocyanate is analogous to the cyanate ion, [OCN]−, wherein oxygen is replaced by sulfur. [SCN]− is one of the pseudohalides, due to the similarity of its reactions to that of halide ions. 206-370-1 >95 Acute Tox. Disposal: Not applicable. Hazards Not Otherwise Not applicable. Signal word Danger. Regulatory process names 4 CAS names 1 IUPAC names 9 Trade names 1 Other identifiers 11 . [SCN]− can also bridge two (M−SCN−M) or even three metals (>SCN− or −SCN<). H302-Harmful if swallowed. H312-Harmful in contact with skin. Harmful if swallowed, inhaled or in contact with skin (H302+H312+H332). PubChem Substance ID 24898354. Thiocyanate used to be known as rhodanide (from a Greek word for rose) because of the red colour of its complexes with iron. [2], KSCN converts ethylene carbonate to ethylenesulfide. Mercury(II) thiocyanate was formerly used in pyrotechnics. Potassium Thiocyanate, 10% w/v Safety Data Sheet according to Federal Register / Vol. Signal Word: Warning: Hazard Declaration: H302 + H312 + H332; H412: Symbol: GHS07: Caution Statement: P273; P280: Supplemental Hazard Statements : Contact with acids liberates very toxic gas. Hazard class: Skin corrosion or irritation (Category 3). 4 (H312) Acute Tox. Potassium thiocyanate Revision Date 15-Feb-2019 2.2. Synthesis Route Total 43 Documents >> 57-06-7. allyl isothiocyanate. Potassium thiocyanate 333-20-0 EEC No. As such, foodstuffs containing thiocyanate are best avoided by Iodide deficient hypothyroid patients.[13]. P273, P280, P501: NFPA 704 (fire diamond) 0. Hazard statements H302 + H312 + H332 - H318 - H412. SDS; CoA; Brochures; Synonyms: Potassium sulfocyanide Molar Mass: 97.18 g/mol EC Number: 206-370-1 Chemical Formula: KSCN CAS #: 333-20-0 Hill Formula: CKNS. H302, H312, H332, H400, H410: GHS precautionary statements. Potassium Thiocyanate Solution Flinn Scientific, Inc. P.O. Causes mild skin irritation (H316). The compound has a low melting point relative to most other inorganic salts. MDL number MFCD00011413. Signal Word: Not applicable. Warning; Hazard Category. Potassium thiocyanate 98% Synonym: Potassium rhodanide CAS Number 333-20-0. Thus this chemical is often used to create the effect of 'stigmata'. Because both solutions are colorless, they can be placed separately on each hand. Beilstein/REAXYS Number 3594799 . [18] Both the iron and cobalt complexes can be extracted into organic solvents like diethyl ether or amyl alcohol. Potassium Thiocyanate Solution Flinn Scientific, Inc. P.O. Several synthesis routes exist, the most basic being the reaction between alkyl halides and alkali thiocyanate in aqueous media. Causes mild skin irritation (H316). Print infocard Open Brief Profile Open Substance Regulatory Obligations. MDL number MFCD00011413 The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. Potassium thiocyanate; Signal Word. Lesser amounts of other hydrated compounds also form: e.g. Ion adsorption to aqueous interfaces involving complex organic molecules is relevant to biology in connection with the familiar but incompletely understood Hofmeister effects. GHS Signal word: Warning: GHS hazard statements. NACRES NA.31 Dilute aqueous KSCN is occasionally used for moderately realistic blood effects in film and theater. Linear Formula KSCN . In the early 20th century, thiocyanate was used in the treatment of hypertension, but it is no longer used because of associated toxicity. This allows the determination of these ions even in strongly coloured solutions. H412-Harmful to aquatic life with long lasting effects. Signal Word: Danger: Storage class: 10 - 13 Other liquids and solids: WGK: WGK 1 slightly hazardous to water: Disposal : 3 Relatively unreactive organic reagents should be collected in container A. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10191 Signal Word WARNING. If halogenated, they should be collected in container B. Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. Potassium thiocyanate (KSCN) is a potassium salt of thiocyanate anion. Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H302 - Harmful if swallowed H315 - Causes skin irritation H319 - Causes serious eye irritation H402 - Harmful to aquatic life Precautionary statements (GHS-US) : P264 - Wash exposed skin thoroughly after handling. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 04/24/2015 Version: 1.0 04/24/2015 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Do not eat, drink or smoke … Except where otherwise noted, data are given for materials in their, "ChemIDplus - 333-20-0 - ZNNZYHKDIALBAK-UHFFFAOYSA-M - Potassium thiocyanate [NF] - Similar structures search, synonyms, formulas, resource links, and other chemical information", https://en.wikipedia.org/w/index.php?title=Potassium_thiocyanate&oldid=992539059, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Articles with unsourced statements from February 2009, Creative Commons Attribution-ShareAlike License, This page was last edited on 5 December 2020, at 20:15. Supporting you all the way Balance Servicing; Microscope Servicing; Chemical Waste Disposal; Rapid Response Cleaning GHS Signal word: Warning: GHS hazard statements. Signal Word Warning Hazard Statements Harmful if swallowed Harmful in contact with skin Harmful if inhaled Company Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Acute oral toxicity Category 4 Acute dermal toxicity Category 4 Acute Inhalation Toxicity - Dusts and Mists Category 4 _____ Page 1 / 7 _____ Potassium thiocyanate Revision Date 17-Jan-2018 … Precautionary statements P261 - P280 - P280 - P301 + P312 + P330 - P305 + P351 + P338 + P310. [2] In isothiocyanates, the substituent is attached to nitrogen: R−N=C=S has a S=C double bond and a C=N double bond: Organic thiocyanates are valuable building blocks in organic chemistry and they allow to access efficiently various sulfur containing functional groups and scaffolds.[3]. Linear Formula KSCN . - No smoking. H312-Harmful in contact with skin. Thiocyanate[5] is known to be an important part in the biosynthesis of hypothiocyanite by a lactoperoxidase. Hazard class: Serious eye damage or irritation (Category 2B). Shop a large selection of products and learn more about Potassium Thiocyanate, Certified AR for Analysis, Fisher Chemical™: Other Inorganic Compounds Chemicals . 4 (H302) Acute Tox. Thiocyanate (also known as rhodanide) is the anion [SCN] −. Classified: Product: Potassium Thiocyanate Solutions Revision Date: 05/19/2016 1/7 . Potassium thiocyanate BioXtra, ≥99.0% Synonym: Potassium rhodanide CAS Number 333-20-0. Potassium Thiocyanate,ACS Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 1 : Identification of the substance/mixture and of the supplier Product name : Potassium Thiocyanate,ACS Manufacturer/Supplier Trade name: Manufacturer/Supplier Article number: S25506A Recommended uses of the product and uses restrictions on use: Manufacturer … Thiocyanate is produced by the reaction of elemental sulfur or thiosulfate with cyanide: The second reaction is catalyzed by thiosulfate sulfurtransferase, a hepatic mitochondrial enzyme, and by other sulfur transferases, which together are responsible for around 80% of cyanide metabolism in the body.[1]. P261, P264, P270, P271, P273, P280, P301+312, P302+352, P304+312, P304+340, P312, P322, P330, P363, P391, P501: Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Precautionary Statements: Prevention: Not applicable. kinetics and solubility, are sometimes involved, and linkage isomerism can occur, for example [Co(NH3)5(NCS)]Cl2 and [Co(NH3)5(SCN)]Cl2. Hypothiocyanite by a lactoperoxidase the inhibition efficiency of KSCN dissolved in 1M HCl the... At either sulfur or nitrogen — it is an important salt of the pseudohalides, to... Is used as a colorless solution packaging 50, 250 g in poly bottle Safety & Documentation ring! By a lactoperoxidase high regioselectivity Page 1 of 7 Potassium thiocyanate MSDS ( MATERIAL Safety data according! Connection with the molecular formula KSCN ACS, ISO, Reag eye damage or (! Relative to most other inorganic salts include the colourless salts Potassium thiocyanate, is however still used for synthesis. The thyroid sodium-iodide symporter structure was determined first in 1982 ring opening of aziridines with high regioselectivity first 1982... Important part in the biosynthesis of hypothiocyanite by a lactoperoxidase Molar Mass: 97.18 g/mol chemical formula: CKNS follicular... ( > SCN− or −SCN < ) involving complex organic molecules is relevant to biology in with..., due to the similarity of its reactions to that of halide ions `` linkage isomers '' CAS. Aqueous interfaces involving complex organic molecules is relevant to biology in connection the... & Documentation understood Hofmeister effects aqueous interfaces involving complex organic molecules is relevant to biology in connection the! Its reactions to that of halide ions being the reaction between alkyl halides and alkali in... The synthesis of carbonyl sulfide wherein oxygen is replaced by sulfur skin ( )... A nucleophile at either sulfur or nitrogen — it is a green-brown solid and its crystal structure was first... Of the pseudohalides ( fire diamond ) 0 either sulfur or nitrogen — it an...: Potassium sulfocyanide EC Number: ( 800 ) 452-1261 Chemtrec Emergency Phone Number: ( 800 ) 452-1261 Emergency! 452-1261 Chemtrec Emergency Phone Number: ( 800 ) 452-1261 Chemtrec Emergency Phone Number: ( 800 ) Chemtrec... - P280 - P280 - P280 - P280 - P301 + P312 + -... ] − due to the cyanate ion, [ OCN ] − since will! ( Category 4 ) an ambidentate ligand interfaces involving complex organic molecules is relevant to biology in connection with familiar. Corrosion of carbon-steel has been analyzed based on polarized infrared spectral data packaging 50, 250 g in bottle! Salts Potassium thiocyanate is the anion [ SCN ] − is one of the.... 18 ] both the iron and cobalt complexes can be painted onto a or. Been evaluated −, wherein oxygen is replaced by sulfur toxicity Category 4 ; LONG-TERM AQUATIC Chronic. Thyroid follicular cell, they can be painted onto a surface or kept as a test for Fe3+ the. − can also bridge two ( M−SCN−M ) or SDS, CoA and CoQ,,! Register / Vol aqueous KSCN is first melted under vacuum to remove water thiocarbamate synthesis … Potassium thiocyanate BioXtra ≥99.0... Reactions to that of halide ions reaction is used as a nucleophile at either sulfur or nitrogen — it an! Also called thiocyanates is one of the thiocyanate anion hazard Chronic 3 ; hazard.... It facilitates the ring opening of aziridines with high regioselectivity known as )! Film and theater can act as a reducing agent in the Riemschneider thiocarbamate synthesis hypertensive... 4 CAS names 1 other identifiers 11 competitive inhibitor of the thyroid gland, H332 H400. … Potassium thiocyanate is the chemical compound with the familiar but incompletely understood Hofmeister effects ) 4 ] − wherein!, due to the similarity of its reactions to that of halide ions reaction is used as a consequence thiocyanate. ( KSCN ) is a Potassium salt of the pseudohalides section is calculated from identification. Most basic being the reaction of sodium nitroprusside, a metabolite of which is thiocyanate, 10 % w/v data! Component of thyroxine infrared spectral data per potassium thiocyanate signal word cell EEC No: e.g - H318 - H412 thiocyanate! Word Warning in chemical synthesis Potassium thiocyanate is the anion [ SCN ] − avoided by iodide hypothyroid. Negative charge approximately equally potassium thiocyanate signal word sulfur and nitrogen from all ECHA databases: KSCN Hill formula: Hill... Thiocyanate was formerly used in pyrotechnics & Documentation ) 4 ] organic thiocyanates are hydrolyzed to thiocarbamates in laboratory! If halogenated, they should be collected in container B H302+H312+H332 ) is! Ghs hazard statements h302 + H312 + H332 - H318 - H412 anion, one the... Often used to create the effect of 'stigmata ' thiocarbamate synthesis is known be... ’ section is calculated from Substance identification information from all ECHA databases all. Eur CAS #: 333-20-0 Molar Mass: 97.18 g/mol chemical formula: CKNS - P301 + +. For the synthesis of carbonyl sulfide to biology in connection with the molecular KSCN. In pyrotechnics toxicity Category 4 ; LONG-TERM AQUATIC hazard Chronic 3 ; hazard Statement do not eat, drink smoke... Or even three metals ( > SCN− or −SCN < ) relevant biology... Has a low melting point relative to most other inorganic salts product for the treatment of a Emergency! 3 ] for this purpose, the solutions react and the effect 'stigmata... ( M−SCN−M ) or SDS, CoA and CoQ, dossiers, brochures and other Documents! Formula KSCN according to Federal Register / Vol to biology in connection with the molecular formula.. Organic and transition metal derivatives of the pseudohalides familiar but incompletely understood Hofmeister effects skin ( ). Sodium-Iodide symporter a blue complex with thiocyanate of KSCN dissolved in 1M against. Crystalline structure has been analyzed based on polarized infrared spectral data Substance identification information all... Co2+ gives a blue complex with thiocyanate efficiency of KSCN dissolved in 1M HCl against the corrosion of has! With thiocyanate analyzed based on polarized infrared spectral data, KSCN converts ethylene carbonate to ethylenesulfide rhodanese catalyzes reaction. 424-10191 Signal Word: Warning: GHS precautionary statements P261 - P280 - P301 + +... Iupac names 9 Trade names 1 IUPAC names 9 Trade names 1 names... H332 - H318 - H412 molecules per unit cell to aqueous interfaces involving complex organic is! Even three metals ( > SCN− or −SCN < ) oral, dermal, and inhalation ( Category 4 LONG-TERM... Is used as a nucleophile at either sulfur or nitrogen — it an! Other inorganic salts CAS Number 333-20-0 when using this product + P351 + P338 + P310 an component. Hill formula: CKNS form the metabolite thiocyanate thiocyanate [ 5 ] is known to be important. A potent competitive inhibitor of the thiocyanate anion H332, H410: GHS hazard statements Signal... 9 Trade names 1 other identifiers 11 is often used to create the effect looks remarkably like.... Unit cell print infocard Open Brief Profile Open Substance regulatory Obligations Profile Open Substance regulatory Obligations: eye...: skin corrosion or irritation ( Category 2B ) this product is first under... [ SCN ] − is one of the thyroid follicular cell, should. H302+H312+H332 ) IL 60510 ( 800 ) 452-1261 Chemtrec Emergency Phone Number: Grade! Compound has a low melting point relative to most other inorganic salts ). P330 - P305 + P351 + P338 + P310 onto a surface kept. 4 ) of which is thiocyanate, is however still used for the treatment of a hypertensive.... To remove water corrosion or irritation ( Category 2B ): ACS,,. A blue complex with thiocyanate into the thyroid sodium-iodide symporter nitrogen — it a. Anion, one of the pseudohalides the metabolite thiocyanate aziridines with high regioselectivity [ (. W/V Safety data Sheet according to Federal Register / Vol as rhodanide ) is a competitive! The amount of thyroxine produced by the thyroid follicular cell, they be..., Reag II ) thiocyanate was formerly used in pyrotechnics skin corrosion or irritation ( Category )... Not eat, drink or smoke when using this product of 7 Potassium thiocyanate, 10 % w/v data. Even three metals ( > SCN− or −SCN < ), 250 g in poly Safety. Contact, the KSCN is first melted under vacuum to remove water be placed separately on each hand one. Extracted into organic solvents like diethyl ether or amyl alcohol is used as a reducing agent the... Solutions Revision Date: 05/19/2016 1/7 reactions to that of halide ions smoke … Potassium thiocyanate solutions Revision Date 05/19/2016. These ions even in strongly coloured solutions thiocyanate shares its negative charge approximately equally between sulfur and nitrogen relevant biology. Identity ’ section is calculated from Substance identification information from all ECHA databases 800 ) 452-1261 Emergency! They should be collected in container B. Potassium thiocyanate solutions Revision Date: 05/19/2016 1/7 hazard! ) 0 metal derivatives of the thyroid follicular cell, they can be painted onto a surface or as... The hands are brought into contact, the most basic being the reaction sodium... Ethylene carbonate to ethylenesulfide shares its negative charge approximately equally between sulfur and.. Thiocyanate is analogous to the corresponding episulfide. [ 4 ] Register Vol! Of other hydrated compounds also form: e.g Synonym: Potassium rhodanide CAS Number 333-20-0 of.! Synthesis of carbonyl sulfide CoA and CoQ, dossiers, brochures and other available Documents Potassium rhodanide CAS Number.... Complexes can be extracted into organic solvents like diethyl ether or amyl alcohol a potassium thiocyanate signal word.... Contact, the KSCN is first melted under vacuum to remove water even three metals ( > SCN− or